Assessing the recycling potential of thermosetting polymer waste in high-density polyethylene composites for safety helmet applications

Author:

Periasamy Diwahar1,Karuppiah Prakalathan1,Manoharan Bharathi2,Arockiasamy Felix Sahayaraj3,Kannan Sathish45,Mohanavel Vinayagam56,Velmurugan Palanivel6,Arumugam Natarajan7,Almansour Abdulrahman I.7,Sivakumar Subpiramaniyam8

Affiliation:

1. Department of Plastic Technology, Central Institute of Petrochemicals Engineering & Technology , Chennai 600 032, Tamil Nadu , India

2. Department of Aeronautical Engineering, KIT-Kalaignarkarunanidhi Institute of Technology , Coimbatore 641 402, Tamil Nadu , India

3. Department of Mechanical Engineering, KIT-Kalaignarkarunanidhi Institute of Technology , Coimbatore 641402, Tamil Nadu , India

4. Department of VLSI Microelectronics, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences , Chennai , 602105, Tamilnadu , India

5. Department of Mechanical Engineering, Amity University , Dubai , 345019 , United Arab Emirates

6. Department of Research, Centre for Materials Engineering and Regenerative Medicine, Bharath Institute of Higher Education and Research, Selaiyur , Chennai , Tamil Nadu 600126 , India

7. Department of Chemistry, College of Science, King Saud University , P.O. Box 2455 , Riyadh 11451 , Saudi Arabia

8. Department of Bioenvironmental Energy, College of Natural Resources and Life Science, Pusan National University , Miryang-si, Gyeongsangnam-do 50463 , Republic of Korea

Abstract

Abstract The rising demand for thermosetting polymers has resulted in the production of large amounts of industrial waste. Environmental issues due to waste landfills and increased raw material costs for new product development have led to the development of innovative recycling methods. This study focuses on the development of a product (helmet shell) by reinforcing thermosetting polymer waste (TPW) as a filler in a high-density polyethylene (HDPE) matrix. The HDPE and TPW were converted into extrudates using a twin-screw extruder. Then, the extrudate was pelletized to use as raw material for the injection molding machine. The HDPE/TPW composites were fabricated using injection molding. Maleic anhydride-grafted polyethylene was employed as a compatibilizer. In the composite, the TPW volume was reinforced at various weight percentages, ranging from 0 to 35 wt%. The mechanical, thermal, and viscoelastic properties of the composites can be enhanced by uniformly dispersing TPW in the HDPE matrix. However, it is difficult to achieve uniform dispersion at higher TPW volumes owing to the agglomeration effect. According to these findings, the mechanical properties were enhanced by up to 30 wt% addition of TPW. The findings suggest that the proposed composite has sufficient mechanical properties to be suitable for the fabrication of helmet shells.

Publisher

Walter de Gruyter GmbH

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