Gamma-ray shielding analysis using the experimental measurements for copper(ii) sulfate-doped polyepoxide resins

Author:

Mahmoud K. A.12,Binmujlli Mazen M.3,Marashdeh M. W.4,Aljaafreh Mamduh J.4,Saleh Ahmad5,Hanfi M. Y.12

Affiliation:

1. Department of Chemical Analysis, Production Sector, Nuclear Materials Authority , 530 Maadi , Cairo , Egypt

2. Department of Nuclear Power Plants and Renewable Energy Sources, Ural Power engineering institute, Ural Federal University , Ekaterinburg 620002 , Russia

3. Department of Internal Medicine, College of Medicine, Imam Mohammad Ibn Saud Islamic University (IMSIU) , Riyadh , 11623 , Saudi Arabia

4. Department of Physics, College of Sciences, Imam Mohammad Ibn Saud Islamic University (IMSIU) , Riyadh , 11623 , Saudi Arabia

5. Department of Mathematics and Natural Sciences, Prince Mohammad Bin Fahd University , Al Khobar, 31952 , Saudi Arabia

Abstract

Abstract The present work aims to study the effect of the CuSO4 additive on the physical and radiation-shielding properties of polyepoxide resins. As a result, a series of four samples with the chemical composition xCuSO4 + (100 − x) (epoxy resin and hardener) was synthesized. The fabrication of samples was performed under atmospheric pressure and at room temperature. The density of the fabricated CuSO4-doped polyepoxides resin was measured experimentally using an MH-300A densimeter with an accuracy of 0.001 mg·cm−3. A narrow beam transmission method with an NaI (Tl) detector was used to evaluate and describe the effect of CuSO4 on the linear attenuation coefficient of the fabricated composites in the γ-ray energy interval, which ranged between 33 and 1,332 keV. The estimated results showed a high enhancement in the µ values that increased from 0.259 to 1.749 cm−1, raising the CuSO4 concentration from 0 to 40 wt% at a γ-photon energy of 33 keV. The enhancement in the µ values decreased with an increase in the γ-photon energy to 1,332 keV, whereas the µ values increased from 0.077 to 0.102 cm−1 with an increase in the CuSO4 concentration between 0 and 40 wt%, respectively. This showed that increased µ values positively affected the half-value thickness (Δ 0.5, cm), mean free path (λ, cm), lead equivalent thickness (Δ eq, cm), and the transmission factor (%); all of the mentioned parameters suffer a considerable decrease with increasing CuSO4 concentration between 0 and 40 wt%.

Publisher

Walter de Gruyter GmbH

Subject

Polymers and Plastics,Physical and Theoretical Chemistry,General Chemical Engineering

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