Evaluation of activated composite membranes for the facilitated transport of phenol

Author:

Pérez-Silva Irma1,Galán-Vidal Carlos A.1,Ramírez-Silva María T.2,Álvarez Romero Giaan A.1,Páez-Hernández Ma. Elena3

Affiliation:

1. Área Académica de Química, Universidad Autónoma del Estado de Hidalgo, Carr. Pachuca-Tulancingo Km. 4.5, C.P. 42184. Mineral de la Reforma, Hidalgo, México

2. Área de Química Analítica, Laboratorio R-105, Universidad Autónoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, C.P. 09340. AP 55-534, Ciudad de México, México

3. Área Académica de Química, Universidad Autónoma del Estado de Hidalgo, Carr. Pachuca-Tulancingo Km. 4.5, C.P. 42184. Mineral de la Reforma, Hidalgo, México, Tel.: +52 7717172000 ext. 2217, +52 7717172000 ext. 6502

Abstract

AbstractIn this work the results on the first use of an activated composite membrane (ACM) containing Cyanex 923 for the extraction and transport of phenol are presented. A new dense layer-ACM configuration constituted by piperazine showed better stability than that prepared with 1,3-phenylenediamine. The effects of several parameters on the transport of phenol such as feed phase pH, carrier concentration and stripping phase composition were evaluated. The performance of the membrane was also evaluated during continuous additions of phenol and for a long period of time, observing the same rate of extraction and reextraction. Moreover, phenol transport was evaluated starting from synthetic wastewater of resin production plants type. The results exhibit the potential use of ACMs in the elimination and transport of organic species, even when analyte is initially found in complex solutions.

Publisher

Walter de Gruyter GmbH

Subject

Polymers and Plastics,Physical and Theoretical Chemistry,General Chemical Engineering

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