Modifying potato starch by glutaraldehyde and MgCl2 for developing an economical and environment-friendly electrolyte system

Abstract

AbstractBiodegradable polymer electrolyte systems are the most sought over option for cheap and energy efficient storage devices. Present paper discusses the results of potato starch + MgCl2 system which satisfy the technical and economic criteria to become a potential candidate for future electrolyte systems. The developed system has high ionic conductivity (~3.43 × 10-2 S/cm), low relaxation time (75 μs) and wide electrochemical stability window (ESW ~4.6 V). The phase angle approaches -79° and maintains its value for 10 Hz to 1 kHz frequency range. The prepared material is a free standing film which can be bended and twisted up to 90°, which makes it suitable for flexible electrochemical device fabrication. The equivalent series resistance (ESR) is quite low (3.41 Ω) and self-resonance frequency below which energy can be efficiently stored is approximately 0.1 MHz. Hence the present study reports an economical, easy to handle and environment friendly electrolyte suitable for electrochemical device fabrication.