Intermediate ytterbium valence in YbRhSn2
Author:
Schumacher Lars1, Engelbert Simon1, Reimann Maximilian Kai1, Kösters Jutta1, Pöttgen Rainer1
Affiliation:
1. Institut für Anorganische und Analytische Chemie , Universität Münster , Corrensstrasse 30, 48149 , Münster , Germany
Abstract
Abstract
The stannide YbRhSn2 has been synthesized. An arc-melted Rh25Sn48 precursor sample was reacted with ytterbium in a sealed tantalum ampoule in an induction furnace. The structure of YbRhSn2 was refined from single-crystal X-ray diffractometer data: MgCuAl2 type, Cmcm, a = 433.10(3), b = 1076.63(8), c = 739.36(5) pm, wR2 = 0.0676, 444 F
2 values and 16 variables. The rhodium and tin atoms form a three-dimensional [RhSn2]
δ−
polyanionic network with short Rh–Sn (271–273 pm) and Sn–Sn (301–324 pm) distances. The tin substructure is an orthorhombically distorted lonsdaleite network. YbRhSn2 shows paramagnetic behavior with a reduced magnetic moment of 2.2(1) µB per ytterbium atom, classifying it as an intermediate-valent compound.
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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