Crystal structure of the oxidotechnetate(V) complex Na2[(TcVO)(OTf)5] · 2(TfOH) with TfOH = trifluoromethanesulfonic acid-Reference-Cited by-同舟云学术

Crystal structure of the oxidotechnetate(V) complex Na₂[(Tc^VO)(OTf)₅] · 2(TfOH) with TfOH = trifluoromethanesulfonic acid

Published:2023-05-12 Issue:6 Volume:78 Page:339-342
ISSN:0932-0776
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Zegke Markus¹,Raauf Aida¹,Neudörfl Jörg-M.¹,Strub Erik²

Affiliation:

1. Department of Chemistry , University of Cologne , Greinstraße 6, 50939 Cologne , Germany

2. Division of Nuclear Chemistry, University of Cologne , Zülpicher Straße 45, 50674 Cologne , Germany

Abstract

Abstract The autoreduction of ammonium pertechnetate in solutions of trifluoromethanesulfonic acid (triflic acid, TfOH) and trifluoromethanesulfonic anhydride (triflic anhydride, TfOTf) results, in the presence of sodium ions, in the formation of the complex Na2[(TcVO)(OTf)5] · 2(TfOH). Its structure has been determined by single-crystal X-ray diffraction.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2022-0143/pdf

Reference17 articles.

1. Papagiannopoulou, D. J. Labelled Compd. Radiopharm. 2017, 60, 502–520; https://doi.org/10.1002/jlcr.3531.

2. Johannsen, B., Spies, H. Technetium (V) chemistry as relevant to nuclear medicine. In Technetium and Rhenium. Their Chemistry and Its Applications; Yoshihara, K., Omori, T., Eds., Vol. 176, Topics in Current Chemistry, Dunitz J. D., Hafner, K., Ito S., Lehn J.-M., Raymond K. N., Rees C. W., Thiem J., Vögtle F., Series Eds. Springer: Berlin, Heidelberg, 1995; pp. 77–121.

3. Helm, L., Deutsch, K., Deutsch, E. A., Merbach, A. E. Helv. Chim. Acta 1992, 75, 210–217; https://doi.org/10.1002/hlca.19920750119.

4. Deutsch, E., Libson, K. Comments Inorg. Chem. 1984, 3, 83–103; https://doi.org/10.1080/02603598408078131.

5. Johnstone, E. V., Weck, P. F., Poineau, F., Kim, E., Forster, P. M., Sattelberger, A. P., Czerwinski, K. R. Eur. J. Inorg. Chem. 2013, 7, 1097–1104; https://doi.org/10.1002/ejic.201201346.