A four-fold three-dimensional zinc(II) coordination polymer based on 4,4′-bis(2-methyl-imidazolyl)biphenyl and 5-sulfoisophthalate ligands: synthesis, structure and properties
Author:
Jiang Weina1, Zhou Lin1, Jiang Haijian1, Cheng Weiwei1, Xue Yun-Shan2
Affiliation:
1. College of Chemical and Biological Engineering , Nanjing Normal University Taizhou College , Nanjing , 225300 , People’s Republic of China 2. School of Chemistry and Environmental Engineering , Yancheng Teachers University , Yancheng , 224007 , People’s Republic of China
Abstract
Abstract
A Zn(II) coordination polymer, [Zn3(4,4′-BMIBP)3(SIP)2]
n
(1) (4,4′-BMIBP = 4,4′-bis(2-methyl-imidazolyl)biphenyl, H3SIP = 5-sulfoisophthalic acid) was hydrothermally synthesized and structurally characterized. Complex 1 has a (3,4)-connected binodal four-fold three-dimensional topology with a point symbol of {4·62·82·10}2{4·62}2{64·102}. It shows strong fluorescence emission in the solid state and efficient photocatalytic performances to degrade methylene blue (MB) under UV irradiation, the degradation of MB reaching 88% after 50 min.
Funder
Natural Science Foundation of the Jiangsu Higher Education Institutions of China
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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