A zinc(II) complex based on 5-(ethylamino)isophthalic acid and trans-1,2-di(4-pyridyl)ethene with a threefold interpenetrated crystal structure: synthesis, crystal structure and room temperature phosphorescence
Author:
Dou Chang-Xun1, Zhang Xin-Ya1, Yang Xiao-Gang1
Affiliation:
1. College of Chemistry and Chemical Engineering, Henan Key Laboratory of Function-Oriented Porous Materials , Luoyang Normal University , Luoyang , Henan Province , 471934 , P. R. China
Abstract
Abstract
A coordination complex {[Zn(EtAIPA)(dpe)]·H2O}
n
(1), has been synthesized under hydrothermal conditions based on 5-(ethylamino)isophthalic acid (H2EtAIPA) and trans-1,2-di(4-pyridyl)ethene (dpe). The title complex was characterized by elemental analysis, UV/Vis absorption, single-crystal X-ray diffraction and emission properties. The as-prepared complex appears as a puckered 2D (4,4) network, The individual 2D nets are interlocked with each other to form a 3-fold parallel interpenetrated 2D architecture. Time-resolved measurements reveal cyan phosphorescence emission at room temperature.
Funder
National Natural Science Foundation of Chinahttps://grants.nsfc.gov.cn/pmpweb/login Project for Science & Technology Innovation Talents in Universities of Henan Province Scientific Research Projects of Henan Province
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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