peri-Interactions in Naphthalenes, 5 [1]. On the Impact of peri-Stress and Trityl-Stress upon the Length of N+-C Bonds in 1-Azonia-acenaphthene Cations-Reference-Cited by-同舟云学术

peri-Interactions in Naphthalenes, 5 [1]. On the Impact of peri-Stress and Trityl-Stress upon the Length of N+-C Bonds in 1-Azonia-acenaphthene Cations

Published:2001-11-01 Issue:11 Volume:56 Page:1109-1116
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Dyker Gerald¹,Hagel Marcel²,Henkel Gerald²,Köckerling Martin²,Näther Christian³,Petersen Sönke⁴,Schiemenzd Günter Paulus⁵

Affiliation:

1. Fakultät für Chemie der Ruhr-Universität, D-44780 Bochum, Germany

2. Institut für Synthesechemie der Universität Duisburg, D-47048 Duisburg, Germany

3. Institut für Anorganische Chemie der Universität, D-24098 Kiel, Germany

4. Institut für Anorganische Chemie der Universität, D-24098 Kiel, Germany d Institut für Organische Chemie der Universität, D-24098 Kiel, Germany

5. Institut für Organische Chemie der Universität, D-24098 Kiel, Germany

Abstract

In the 1-azonia-acenaphthene salts 6b and 9, the N+-Cperi bond is modestly elongated. While no clear-cut influence of the peri-stress is obvious, incorporation of Cperi in a triarylmethyl structure has a bond-lengthening effect. However, the stretching forces are insufficient to restore the ideal geometry of the naphthalene skeleton.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2001-1103/pdf

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