New π -Donor Molecules with a Pyrazino Group and their Conducting Salts

Author:

Papavassiliou G. C.1,Misaki Yohji2,Takahashi Kazuko3,Yamada Jun-ichi4,Mousdis G. A.1,Sharahata Takashi3,Ise Toshihiro3

Affiliation:

1. Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48, Vassileos Constantinou Ave, Athens 116/35, Greece

2. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 606-01, Japan

3. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-77, Japan

4. Department of Material Science, Faculty of Science, Himeji Institute of Technology, 1475-2 Kanaji, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan

Abstract

Abstract The preparation and characterization of some π-donors with a pyrazine-edge-group as well as with tetrathiapentalene-, thiophene-, and dihydrobenzoselenophene-spacer-groups are de­ scribed. Some of these donors give conducting charge transfer complexes with TCNQ and/or cation radical salts with I3 -, BF4 -and PF6 -as counter anions.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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