Hexakis(dimethylaminoxy)disiloxane: Insertion of an Oxygen Atom into the Si-Si Bond of a Disilane by Dimethylaminoxy Lithium-Reference-Cited by-同舟云学术

Hexakis(dimethylaminoxy)disiloxane: Insertion of an Oxygen Atom into the Si-Si Bond of a Disilane by Dimethylaminoxy Lithium

Published:2001-07-01 Issue:7 Volume:56 Page:630-633
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Mitzel Norbert W.¹,Losehand Udo¹

Affiliation:

1. Anorganisch-chemisches Institut, Technische Universität München, Lichtenbergstr. 4, D-85747 Garching

Abstract

Abstract The compound (Me2NO)3SiOSi(ONMe2)3 was prepared by the reaction of LiONMe2 with Si2Cl6, a reaction in which oxygen is inserted into the Si-Si bond. The crystal structure of (Me2NO)3SiOSi(ONMe2)3 was determined and shows the compound to have a linear siloxane core and SiON units with small valence angles at oxygen, caused by weak Si (-N interactions leading to partially hypercoordinate Si centres.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2001-0711/pdf

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