Affiliation:
1. Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-70569 Stuttgart, Germany
Abstract
Abstract
The solid state synthesis and the crystal structure of Cs6Cl4O(Pearson-code hR22, R3c, a = 1324.7(6), c = 1658(1) pm, Z = 6, 931 reflections with Io > 2σ(I), R1 = 0.040, wR2 = 0.114) are reported. The compound crystallises isotypically with Rb6Cl4O in the anti-K4CdCl6 type of structure. The structure consists of infinite chains of alternating face-sharing OCs6 octahedra and ClCs6 trigonal prisms which are separated by chloride anions. The underlying structural concept and the analogy to perovskites are outlined.
Cited by
9 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献