On Barium Oxide Solubility in Barium-Containing Chloride Melts

Author:

Nikolaeva Elena V.1,Zakiryanova Irina D.1,Bovet Andrey L.1,Korzun Iraida V.2

Affiliation:

1. Institute of High Temperature Electrochemistry, Ural Federal University, Yekaterinburg, Russian Federation

2. Institute of High Temperature Electrochemistry, Yekaterinburg, Russian Federation

Abstract

Abstract Oxide solubility in chloride melts depends on temperature and composition of molten solvent. The solubility of barium oxide in the solvents with barium chloride content is essentially higher than that in molten alkali chlorides. Spectral data demonstrate the existence of oxychloride ionic groupings in such melts. This work presents the results of the BaO solubility in two molten BaCl2–NaCl systems with different barium chloride content. The received data together with earlier published results revealed the main regularities of BaO solubility in molten BaO–BaCl2–MCl systems.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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