Crystal structure and physical properties of a new two-dimensional zinc coordination polymer based on 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine and benzophenone-2,4′-dicarboxylate ligands
Author:
Zhang Xin-Yue1, Zhang Chen1, Wang Jun1, Xu Xiao-Juan2
Affiliation:
1. School of Chemistry & Environmental Engineering, Yancheng Teachers University , Yancheng , Jiangsu 224051 , P. R. China 2. College of Pharmacy, Yancheng Teachers University , Yancheng , Jiangsu 224051 , P. R. China
Abstract
Abstract
A new 2-dimensional (2D) zinc(II) coordination polymer based on a flexible bis(imidazole) ligand, namely, [Zn2(BIBP)(BPDC)2·DMF]
n
(1) BIBP is 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine and H2BPDC is benzophenone-2,4′-dicarboxylic acid), has been synthesized and characterized through single-crystal X-ray diffraction, infrared (IR) spectroscopy, and elemental and thermal gravimetric analysis. Complex 1 exhibits a 2D framework oriented parallel to [0 2 1] based on [Zn(BPDC)]
n
chains. The fluorescence and catalytic properties of complex 1 for the photodegradation of methylene blue were investigated.
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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