A novel three-dimensional cadmium sulfate-based inorganic-organic hybrid polymer with green photoluminescence-Reference-Cited by-同舟云学术

A novel three-dimensional cadmium sulfate-based inorganic-organic hybrid polymer with green photoluminescence

Published:2020-12-23 Issue:1 Volume:76 Page:79-84
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Zhang Tong¹,Zhao Zhen¹,Tang Yao¹,Liu Jing-Si¹,Huang Gui-Lin¹,Liu Xi¹

Affiliation:

1. Chongqing Key Laboratory of Green Synthesis and Applications , College of Chemistry, Chongqing Normal University , Chongqing , 401331, P. R. China

Abstract

Abstract Layer diffusion of 3,5-bis(4-pyridyl)-1H-1,2,4-triazole (BptH) in ethanol on an aqueous solution of cadmium sulfate leads to a novel three-dimensional cadmium sulfate-based inorganic-organic hybrid polymer (IOHP), CdSO4(H2O)(BptH)·1.5H2O (1). Its structure was determined by single-crystal X-ray diffraction (SCXRD), and further characterized by elemental analysis, powder X-ray diffraction (PXRD), infrared spectra (IR), and thermogravimetric (TG) analysis. IOHP 1 exhibits a novel 2-nodal 3,5-connected nanoporous structure formed by BptH ligands connecting 2D neutral inorganic cadmium sulfate layers. Water molecules reside in its nanoporous channels. The thermal stability and solid-state photoluminescence properties of the compound have also been investigated.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Chongqing

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2020-0160/pdf

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