Diethyl (iodoethynyl)phosphonate and (iodoethynyl)diphenylphosphane oxide: crystal structures and some cycloaddition reactions
Author:
Marian Aline1, Maas Gerhard1ORCID
Affiliation:
1. Institute of Organic Chemistry I , Ulm University , Albert-Einstein-Allee 11 , D-89081 Ulm , Germany
Abstract
Abstract
The title compounds are difunctionalized acetylenic building blocks, which can serve as electrophilic dienophiles and dipolarophiles in [4+2] and azide-iodoalkyne [3+2] cycloaddition reactions, which, however, require strong thermal activation. In their crystal structures, they are self-complementary tectons, which are arranged in polymeric chains maintained by very short intermolecular Csp–I···O=P halogen bonds.
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
Reference34 articles.
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