Al5B12O25(OH) and Ga4InB12O25(OH) – two additional triel borates with the structure type M 5B12O25(OH) (M = Ga, In)-Reference-Cited by-同舟云学术

Al5B12O25(OH) and Ga4InB12O25(OH) – two additional triel borates with the structure type M 5B12O25(OH) (M = Ga, In)

Published:2020-07-01 Issue:6-7 Volume:75 Page:605-613
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Vitzthum Daniela¹,Wimmer Daniel S.¹,Widmann Ingo¹,Huppertz Hubert¹

Affiliation:

1. Institut für Allgemeine, Anorganische und Theoretische Chemie , Universität Innsbruck , Innrain 80–82 , 6020 Innsbruck , Austria

Abstract

Abstract The isotypic triel borates Al5B12O25(OH) and Ga4InB12O25(OH) were synthesized in a Walker-type multianvil apparatus under high-pressure/high-temperature conditions of 12.0 GPa/1400 °C and 12.3 GPa/1200 °C, respectively. The crystal structures of both compounds, determined by single-crystal X-ray diffraction, constitute new representatives of the structure type M 5B12O25(OH) (M = Ga, In) crystallizing in the space group I41/acd. The presence of the hydroxyl groups was confirmed via single-crystal IR spectroscopy.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2020-0075/pdf

Reference31 articles.

1. Vitzthum, D., Wurst, K., Pann, J. M., Brüggeller, P., Seibald, M., Huppertz, H. Angew. Chem. Int. Ed. 2018, 57, 11451–11455; https://doi.org/10.1002/anie.201804083.

2. Vitzthum, D., Wurst, K., Pann, J. M., Brüggeller, P., Seibald, M., Huppertz, H. Angew. Chem. 2018, 130, 11622–11626; https://doi.org/10.1002/ange.201804083.

3. Bither, T. A., Young, H. S. J. Solid State Chem. 1973, 6, 502–508; https://doi.org/10.1016/S0022-4596(73)80006-4.

4. Cox, J. R., Keszler, D. A. Acta Crystallogr. 1994, C50, 1857–1859; https://doi.org/10.1107/S0108270194003999.

5. Vitzthum, D., Huppertz, H. Z. Naturforsch. 2019, 74b, 357–363; https://doi.org/10.1515/znb-2019-0014.

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Expansion and adaptation of the M ₅B₁₂O₂₅(OH) structure type to incorporate di- and trivalent transition metal cations;Zeitschrift für Naturforschung B;2024-01-01

2. Crystal Structure of c ‐ M 5 B 12 O 25 (OH) ( M =Al, Al/Ga, Ga/In) – Three Disordered Cubic Trielborates Synthesized under High‐Pressure Conditions;European Journal of Inorganic Chemistry;2021-03-09

3. High-pressure synthesis and crystal structure of HP-Al2B3O7(OH);Zeitschrift für Naturforschung B;2020-10-12