Synthesis and structural characterization of substituted phenols with a m-terphenyl backbone 2,4,6-R3C6H2OH (R=2,4,6-Me3C6H2, Me5C6)

Author:

Şolea Atena B.1,Olaru Marian1,Silvestru Cristian1,Raţ Ciprian I.1

Affiliation:

1. Centre of Supramolecular Organic and Organometallic Chemistry, Faculty of Chemistry and Chemical Engineering, Department of Chemistry, Babeş-Bolyai University, 11 Arany Janos Street, 400028 Cluj-Napoca, Romania

Abstract

Abstract Substituted phenols with a m-terphenyl backbone 2,4,6-R3C6H2OH [R=2,4,6-Me3C6H2 (1), Me5C6 (2)] were synthesized using Kumada cross-coupling reactions between 2,4,6-I3C6H2OH and the corresponding Grignard reagent. Both compounds were structurally characterized in solution by 1H and 13C NMR spectroscopy and HRMS. The molecular structures of 1 and 2 were determined by single-crystal X-ray diffraction.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Advances in Kumada–Tamao–Corriu cross-coupling reaction: an update;Monatshefte für Chemie - Chemical Monthly;2019-03-07

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