Affiliation:
1. Physikalisches Institut der Universität Tübingen 7400 Tübingen, Morgenstelle, Germany
Abstract
Abstract
Fourier transform NMR studies of 17O, 35Cl, 51V, 53Cr, 55Mn and 95Mo are reported for aqueous solutions of the oxyanions ClO4
-, VO4
3-, CrO4
2-, MnO4
-, and MoO4
2-, partly enriched in 17O. The indirect spin-spin coupling constant between 17O and the quadrupolar central nucleus is determined:
A linear dependence of the reduced coupling constants on the atomic number of the central nucleus in the isoelectronic series VO4
3-, CrO4
2- and MnO4
- was found.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
51 articles.
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