Affiliation:
1. Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Kraków, Poland
Abstract
The behaviour of a system composed of malonic acid (MA), KBrO3, H2SO4, and ferroin was investigated in batch experiments at various concentrations of oxygen above the chemical mixture when changing the concentration of MA. We could observe that at 10% of oxygen or more and for initial concentrations of malonic acid [MA]0 between 0.15 M and 0.6 M the system attains an equilibrium by some of mixed mode oscillations. Such a behaviour of the system could be described by a model used lately. Additionally for [MA]0 = 0.1 M or less at 0 - 20% of oxygen a region of sequential oscillations was discovered (observed for the first time in the system with ferroin) and a trial of understanding of the event is suggested. For rather small [MA]0 ca. 0.025 M no mixed mode oscillations, no sequential ones but the so-called relaxation oscillations were observed.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
7 articles.
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