Affiliation:
1. Chemisches Laboratorium der Universität Freiburg
Abstract
Abstract
The monomeric complex Cp(CO)3Cr (2) is formed in benzonitrile solution by electrochemical oxidation of the anion Cp(CO)3Cr- (3) or by dissolution of the parent dimer Cp(CO)3Cr-Cr(CO)3Cp (1). Its existence is obvious from electrochemical and ESR data which together with the IR and NMR spectra indicate that in this solution the dimer 1 is in a rapid equilibrium with about 1% of the monomer 2.
Cited by
79 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Seventeen-electron compounds in an eighteen-electron world – An historical perspective;Journal of Organometallic Chemistry;2014-02
2. [Re(η5-C5H5)(CO)3]+ Family of 17-Electron Compounds: Monomer/Dimer Equilibria and Other Reactions;Journal of the American Chemical Society;2008-02-01
3. Coupling of CpCr(CO)3 and Heterocyclic Dithiadiazolyl Radicals. Synthetic, X-ray Diffraction, Dynamic NMR, EPR, CV, and DFT Studies;Inorganic Chemistry;2007-12-28
4. One-Electron Oxidations of the Methyldiphenylphosphonium Cyclopentadienylide Complexes M(η5-C5H4PMePh2)(CO)3 (M = Cr, Mo, W): Formation and Dimerization of the 17-Electron, Metal-Centered Radicals [M(η5-C5H4PMePh2)(CO)3]+;Organometallics;2007-10-19
5. A tert-butyl/cyano substituted (1,2,3,5-dithiadiazolyl)benzene and η2 π complexes with CpCr(CO)2;Journal of Organometallic Chemistry;2007-06