Experimentelle Prüfung von Näherungsansätzen für Chiralitätsfunktionen am Beispiel der optischen Aktivität von Methan-Derivaten im Transparenzgebiet II / Semiempirical Use of Chirality Functions for the Description of the Optical Activity of Methan Derivatives in the Transparent Region II

Abstract

Simple alcohol derivatives are used to test approximative chirality functions experimentally. The approximations of the type 1 b yield a competent description of the optical rotatory power of methan-derivatives. Provided that certain restrictions of ligand inter-actions are taken into account, a set of ligand-specific parameters is obtained; however, no common set of parameters is suitable for both the alcohol and the amino-alcohol derivatives, which have been published before