Affiliation:
1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule Darmstadt
Abstract
Abstract
CaAl2Se4 and SrAl2Se4 have been prepared and their crystal structures determined. They crystallize orthorhombically, space group Cccm, with the lattice constants:
CaAl2Se4: a = 633 ± 1pm, b = 1048 ± 1pm, c = 1053 ± 1pm;
SrAl2Se4: a = 627 ± 1 pm, b = 1082 ± 1 pm, c = 1085 ± 1 pm.
The structures of these compounds are closely related both to each other and to the TlSe-structure.
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