Fluorierung von Platin(IV)amminkomplexen in wäßriger Lösung / Fluorination of Ammine Complexes of Platinum(IV) in Aqueous Solution

Abstract

Abstract Unlike chlorination fluorination of ammine complexes of platinum(IV) in aqueous solution does not lead to haloamido complexes. Instead, the triammine complexes [Pt(NH3)3Cl3]Cl and [Pt(NH3)3(NCl2)2Cl]Cl yield no definite main product, and the tetrammine and pentammine complexes trans-[Pt(NH3)4Cl2]Cl2, [Pt(NH3)4(NCl2)Cl]Cl2, [Pt(NH3)5Cl]Cl3, and [Pt(NH3)5(OH)]Cl3 form the sparingly soluble complex trans -[Pt (NH3)4Cl2](H2F3)2 · 2H2O as the main product.