Tri(tert-butyl)phosphinoxid, -imin, -methylen und -boran / Tri(tert-butyl)phosphine Oxide, Imine, Methylene and Borane-Reference-Cited by-同舟云学术

Tri(tert-butyl)phosphinoxid, -imin, -methylen und -boran / Tri(tert-butyl)phosphine Oxide, Imine, Methylene and Borane

Published:1978-12-01 Issue:12 Volume:33 Page:1556-1558
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Schmidbaur Hubert¹,Blaschke Günter¹

Affiliation:

1. Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-8046 Garching

Abstract

Abstract Tri(tert-butyl)phosphine Oxide, Imine, Methylene, Borane Tri(tert-butyl)phosphine oxide, imine, methylene and borane have been prepared and their properties investigated. The imine is chemically inert due to strong steric hindrance. Its thermal decomposition at 200 °C leads to tri(tert-butyl)-pliosphine, in contrast to the methylene analogue which undergoes reductive elimination of isobutene. Both the oxide and borane are thermally very stable (> 250 °C).

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1978-1239/pdf

Cited by 8 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Neuartige Cyclopentadienyl-N-silylphosphazen-Komplexe der Seltenerdmetalle Yttrium und Lutetium. New Cyclopentadienyl-N-Silylphosphazene Complexes of Rare-Earth Metals Yttrium and Lutetium;Zeitschrift für anorganische und allgemeine Chemie;2010-06-08

2. And Compounds with P-B Bonds;Inorganic Reactions and Methods;2007-05-29

3. A new family of monocyclopentadienyl organoscandium bis-alkyls supported by a bulky trialkylphosphine oxide ancillary;Canadian Journal of Chemistry;2004-02-01

4. Alkylphosphorus Compounds;Comprehensive Organic Functional Group Transformations;1995

5. References to Volume 2;Comprehensive Organic Functional Group Transformations;1995