N.N' -Dimethylacetamidinderivate des Aluminiums, Galliums und Indiums / N,N'-Dimethylacetamidin Derivatives of Aluminium, Gallium and Indium

Author:

Gerstner Franz1,Weidlein Johann1

Affiliation:

1. Institut für Anorganische Chemie der Universität Stuttgart

Abstract

Abstract The interaction of N,N'-dimethylacetamidine with trialkyl derivatives of aluminium, gallium and indium yields dialkylmetal compounds of the structural formula R2M(N2Me2CMe) (M = Al, Ga and In). According to the vibrational data the M2N4C2 skeletons of these dimeric products form a centrosymmetric puckered eight-membered ring, probably with C2h symmetry. The IR-and Raman spectra of the amidine HN(Me)C(= NMe)Me are discussed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 29 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Synthesis and Structure of Novel Bridged Dinuclear Indium Complexes;Inorganic Chemistry;1996-01-01

2. Synthesis and Structure of Metal-Containing Eight- and Twelve-Membered M‒N‒C‒O‒Heterocycles (M = Al, Ga, In);Main Group Chemistry;1995-09

3. Five-Coordinate Organometallic Complexes of Gallium and Indium;Organometallics;1995-07

4. References to Volume 5;Comprehensive Organic Functional Group Transformations;1995

5. Amidines and N-Substituted Amidines;Comprehensive Organic Functional Group Transformations;1995

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