Neue Intercalationskomplexe von Eisen(III)oxichlorid, FeOCl / New Intercalation Complexes of Iron(III) Oxichloride, FeOCl

Author:

Weiss Armin1,Sick E.1

Affiliation:

1. Institut für Anorganische Chemie, Universität München

Abstract

Abstract Nonstoichiometric iron (III) oxichloride is capable of intercalating a large number of guest molecules with Lewis base character, e.g. dimethylsulfoxide, formamide, hexa-methylphosphortriamide, or alkylamines, while the reactions of stoichiometric FeOCl are restricted to pyridine and its derivatives only. The nonstoichiometric host lattice can be synthesized either by direct reaction form Fe2O3, FeCl3 and Fe or by reduction of the stoichiometric compound. In the latter case the basal spacings of the intercalation complexes depend upon the degree of reduction and the electrolyte concentration. The highly expanded lattice is rapidly hydrolyzed in the presence of water.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 26 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3