Notizen: Neue Derivate des Schwefelhexafluorids. Pentafluorschwefeloxiddifluoridimid F5S-NS(O)F2 und Pentafluorschwefeldimethylamid F5S-N(CH3)2 / New Derivatives of Sulfurhexafluoride. Pentafluorosulfuroxidedifluorideimide F5S-NS(O)F2 and Pentafluorosulfurdimethylamide F6S-N(CH3)2

Abstract

NSF3 reacts with OSF4 to give F5S-NSOF2 which hydrolyses with alkali to the ion [F5S-NSO2F]-. From NSF2-N(CH3)2 and SF4 or OSF4 only F5S-N(CH3)2 is received together with decomposition products NSF resp. (NSOF)3.