Reaktionen von Pentafluorbenzolsulfen-, -sulfin- und -sulfonsäurechlorid mit Natrium-bis(trimethylsilyl)-amid / Reactions of Pentafluorobenzenesulfenyl, -sulfinyl, and -sulfonyl Chlorides with Sodium-bis(trimethylsilyl) Amide

Abstract

By reaction with NaN[Si(CH3)3]2, the chlorides C6F5SCl, C6F5S(O)Cl, and C6F5SO2Cl are converted into C6F5SN[Si(CH3)3]2, C6F5S(O)N[Si(CH3)3]2, and Na+[C6F5SO2]-, respectively. In this instance the reactivity pattern of the pentafluorophenyl compounds does not differ from that of similar phenyl derivatives.