Platinum Blues - a Study of the Interaction between Potassium Tetrachloroplatinate and Asparagine-Reference-Cited by-同舟云学术

Platinum Blues - a Study of the Interaction between Potassium Tetrachloroplatinate and Asparagine

Published:1980-12-01 Issue:12 Volume:35 Page:1508-1510
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Arrizabalaga Philippe¹,Castan Paule¹,Laurent Jean-Pierre¹

Affiliation:

1. Laboratoire de Chimie de Coordination du CNRS associé à l’Université Paul Sabatier, 205 route de Narbonne, 31400 Toulouse, France

Abstract

Abstract Potassium tetrachloroplatinate and asparagine form a paramagnetic complex in aqueous solution. This complex which displays a blue green color has been studied by ESR and IR spectroscopy. The ESR spectra are interpreted to be due to tervalent platinum in a low spin d7 configuration. The IR data suggest that the doubly deprotonated ligand is coordinated through the COO- and CONH- groups.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1980-1203/pdf

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