Affiliation:
1. Institut für Anorganische und Analytische Chemie I, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 58, D-6300 Gießen
Abstract
Abstract
Tetrachloroaluminates, -ferrates and -gallates of formulae AIMIIICL4 with A1 = Cs, Rb, In, Tl, NH4 as well as the high temperature forms of the potassium compounds (KMIIICl4-III) crystallize with the baryte type structure. LiMIIICL4, NaMIIICl4, and KMIIICl4-II (MIII = AI, Fe, Ga), isotypic among themselves, belong -dependent on the size of the A+ ion -to three different structure types.
Cited by
26 articles.
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1. On the Synthesis and Structure of ‘Naked’ Ga(I) and In(I) Salts and the Surprising Stability of Simple Ga(I) and In(I) Salts in the Coordinating Solvents Ether and Acetonitrile;Chemistry – A European Journal;2024-05-06
2. Lithium tetrachloridoaluminate, LiAlCl4: a new polymorph (oP12,Pmn21) with Li+in tetrahedral interstices;Acta Crystallographica Section E Crystallographic Communications;2017-09-08
3. Synthesis and Characterization of Bimetallic Single‐Source Precursors (Ph
3
P)
2
M(µ‐SEt)
2
E(SEt)
2
for MES
2
Chalcopyrite Materials (M = Cu, Ag and E = In, Ga, Al);European Journal of Inorganic Chemistry;2017-04-03
4. Synthesis, Spectroscopic Characterization, Crystal Structures, Energetics, and Thermal Stabilities of Li[AlX
4
] (X = Cl, Br): Investigation and Performance of Their Electrolyte Solutions;European Journal of Inorganic Chemistry;2015-06-16
5. Optical properties of the Bi+ center in KAlCl4;Journal of Luminescence;2014-07