Affiliation:
1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule in Darmstadt, Hochschulstraße 4, D-6100 Darmstadt
Abstract
Abstract
The new compound CaMnBi2 has been analytically and structurally characterized. CaMnBi2 crystallizes in the tetragonal system (a = 450 ± 1 pm, c = 1108 ± 2 pm, space group P4/nmm). Mn and Bi atoms form fourfold pyramids, connected by common edges in the basis to two-dimensional sheets. These sheets are separated by double layers of Ca atoms between which further Bi atoms are located forming squarenets. The structure is strongly related to that of SrZnSb2 which can be interpreted as a distorted variant of the new CaMnBi2 type.
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