Organometallphosphin-substituierte Übergangsmetallkomplexe, XXVI [1] Diearbonyl-nitrosyl-organometaUphosphin-kobalt-Komplexe / Organometalphosphine-Substituted Transition Metal Complexes, XXVI [1] Dicarbonyl Nitrosjd Organometal Phosphine Cobalt Complexes

Abstract

Abstract The reactions of tricarbonyl nitrosyl cobalt with tri-tert-butylphosphine, di(tert-butyl)-trimethylsilyl-, -germyl-, -stannylphosphine, tert-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl)phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl-phosphine result in the elimination of one CO-ligand and the formation of corresponding dicarbonyl-nitrosyl-organometal phosphine cobalt complexes. The NMR spectra of the products are reported and discussed.