Affiliation:
1. Institut für Anorganische und Analytische Chemie, Technische Universität Berlin, D-1000 Berlin 12
Abstract
A redetermination of the crystal and molecular structure of the chain-like molecule S(NSO)2 resulted in the following molecular parameters: d(SO) = 146.5(2), d(S = N) = 153.4(2), d(S-N) = 165.7(2) pm, bond angles OSN = 117.5(1)°, SNS = 123.6(2)°, and NSN = 97.2(1)°, torsion angles OSNS = -0.3(2)°, and SNSN = -177.7(2)° (molecular symmetry C2). Infrared and Raman spectra of S(NSO)2 are reported and assigned; there is no evidence for conformational changes on dissolution of crystalline S(NSO)2
Cited by
37 articles.
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1. Chalcogen–Nitrogen Oxides;A Guide to Chalcogen-Nitrogen Chemistry;2005-01
2. N-Sulfinylimine compounds, R–NSO: a chemistry family with strong temperament;Journal of Molecular Structure;2000-04
3. Synthese der Sulfinylamine (CH3)3NB(NSO)3, (C6F5)2E(NSO)y, (E, y: P, 1; Te, 2), (Rf)nGe(NSO)4−n, (Rf, n: CF3, 3,2; C6F5, 3,2,1,0), (C6F5)3SnNSO, Si(NSO)4 und F4SbNSO: Charakterisierung und chemisches Verhalten;Journal of Fluorine Chemistry;1999-07
4. Bis(sulfinylamino)selane, Se(NSO)2: between S(NSO)2 and Te(NSO)2 in theoretical and spectroscopical considerations;Journal of Molecular Structure;1999-03
5. Structural and spectroscopic characterization of ClC(O)SNSO. A theoretical and experimental study;Physical Chemistry Chemical Physics;1999