Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), {[Ag2(Imt)3](NO3)2} n-Reference-Cited by-同舟云学术

Crystal structure of a new silver(I) coordination polymer assembled from imidazolidine-2-thione (Imt), {[Ag2(Imt)3](NO3)2} n

Published:2019-07-11 Issue:7-8 Volume:74 Page:565-569
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Ahmad Saeed¹,Seerat-ur-Rehman ²,Arshad Muhammad Nadeem³⁴,Asiri Abdullah M.³⁴,Rüffer Tobias⁵,Choudhary Muhammad Aziz²,Isab Anvarhusein A.⁶

Affiliation:

1. Department of Chemistry, College of Sciences and Humanities , Prince Sattam bin Abdulaziz University , Al-Kharj 11942 , Saudi Arabia

2. Department of Chemistry , Mirpur University of Science and Technology , Mirpur , AJK , Pakistan

3. Department of Chemistry, Faculty of Science , King Abdulaziz University , P.O. Box 80203 , Jeddah 21589 , Saudi Arabia

4. Center of Excellence for Advanced Materials Research (CEAMR) , King Abdulaziz University , P.O. Box 80203 , Jeddah 21589 , Saudi Arabia

5. Inorganic Chemistry Division, Institute of Chemistry, Faculty of Natural Sciences , Technische Universität Chemnitz , 09107 Chemnitz , Germany

6. Department of Chemistry , King Fahd University of Petroleum and Minerals , Dhahran 31261 , Saudi Arabia

Abstract

Abstract A new polymeric silver(I) complex of imidazolidine-2-thione (Imt), {[Ag2(Imt)3](NO3)2} n (1) was prepared and its structure was determined by single-crystal X-ray diffraction analysis. The silver atoms form infinite chains with two Ag − S(Imt) − Ag strands linked to each other by sulfur atoms of μ 4-Imt ligands. Each silver(I) ion is bound to four sulfur atoms of bridging Imt ligands in a distorted tetrahedral environment. The crystal structure is stabilized by hydrogen bonding and weak argentophilic interactions. The hydrogen bonded nitrate ions connect the 1D chains to generate a 2D layer structure.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2019-0065/pdf

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