A MOF based on a lead(II) 2-oxido-6-methylpyridine-4-carboxylate network-Reference-Cited by-同舟云学术

A MOF based on a lead(II) 2-oxido-6-methylpyridine-4-carboxylate network

Published:2020-03-05 Issue:4 Volume:75 Page:365-369
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Tang Long¹,Fu Yu Pei¹,Cui Na¹,Wang Ji Jiang¹,Hou Xiang Yang¹,Wang Xiao¹

Affiliation:

1. Yan’an University Key Laboratory of New Energy and New Functional Materials , Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University , Yan’an 716000 , P.R. China

Abstract

Abstract A new metal-organic framework, [Pb(hmpcaH)2] n (1), has been hydrothermally synthesized from Pb(OAc)2 · 3H2O and 2-hydroxy-6-methylpyridine-4-carboxylic acid (hmpcaH2; 2), and characterized by IR spectroscopy, elemental and thermogravimetric analysis, and single-crystal X-ray diffraction. In complex 1, each hmpcaH− ligand represents a three-connected node to combine with the hexacoordinated Pb(II) ions, generating a 3D binodal (3,6)-connected ant network. The crystal structure of 2 was determined. The solid-state fluorescence properties of 1 and 2 were investigated.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2019-0208/pdf

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