Synthesis and molecular structure of [Rh(η 5-C5H5)(coe)(PtBu2H)] (coe=cis-cyclooctene)

Author:

Böttcher Hans-Christian1,Mayer Peter1,Beck Daniel1

Affiliation:

1. Department Chemie der Ludwig-Maximilians-Universität , Butenandtstraße 5–13 , 81377 München , Germany

Abstract

Abstract The synthesis and structural characterization of the new olefinic complex [Rh(η 5-C5H5)(coe)(PtBu2H)] (2, coe = cis-cyclooctene) is reported. The title compound was easily prepared in good yield by a thermolytic approach using [Rh(η 5-C5H5)(coe)2] (1) and the secondary phosphane in toluene under reflux conditions. The compound 2 has been characterized by NMR spectroscopy and microanalysis. Single crystals of 2 were grown from n-hexane and the molecular structure has been established by X-ray diffraction.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. An Entry to Double Phosphanyl‐Bridged Dinuclear Rhodium(II) Complexes;European Journal of Inorganic Chemistry;2019-05-15

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