Synthesis and molecular structure of [Rh(η 5-C5H5)(coe)(PtBu2H)] (coe=cis-cyclooctene)-Reference-Cited by-同舟云学术

Synthesis and molecular structure of [Rh(η 5-C5H5)(coe)(PtBu2H)] (coe=cis-cyclooctene)

Published:2019-04-18 Issue:5 Volume:74 Page:455-457
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Böttcher Hans-Christian¹,Mayer Peter¹,Beck Daniel¹

Affiliation:

1. Department Chemie der Ludwig-Maximilians-Universität , Butenandtstraße 5–13 , 81377 München , Germany

Abstract

Abstract The synthesis and structural characterization of the new olefinic complex [Rh(η 5-C5H5)(coe)(PtBu2H)] (2, coe = cis-cyclooctene) is reported. The title compound was easily prepared in good yield by a thermolytic approach using [Rh(η 5-C5H5)(coe)2] (1) and the secondary phosphane in toluene under reflux conditions. The compound 2 has been characterized by NMR spectroscopy and microanalysis. Single crystals of 2 were grown from n-hexane and the molecular structure has been established by X-ray diffraction.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2019-0041/pdf

Reference9 articles.

1. M. Graf, H.-C. Böttcher, P. Mayer, M. Scheer, Z. Anorg. Allg. Chem.2017, 643, 1323.

2. H.-C. Böttcher, P. Mayer, Z. Anorg. Allg. Chem.2017, 643, 1107 and references cited therein.

3. R. Cramer, J. Am. Chem. Soc.1967, 89, 5377.

4. J. F. Nixon, A. A. Pinkerton, J. Organomet. Chem.1972, 37, C47.

5. S. T. Belt, S. B. Duckett, D. M. Haddleton, R. N. Perutz, Organometallics1989, 8, 748.

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