Synthesis, crystal structure and photoluminescence of a binuclear rhenium(I) carbonyl complex incorporated in a framework of a distorted salophen ligand-Reference-Cited by-同舟云学术

Synthesis, crystal structure and photoluminescence of a binuclear rhenium(I) carbonyl complex incorporated in a framework of a distorted salophen ligand

Published:2020-11-24 Issue:12 Volume:75 Page:1061-1064
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Vogler Arnd¹,Bodensteiner Michael¹

Affiliation:

1. Institute of Inorganic Chemistry, University of Regensburg , Universitätsstr. 31 , 93053 Regensburg , Germany

Abstract

Abstract Re(CO)5Cl reacts with salophenH2 to yield Re(I)2(salophenH)(CO)6Cl. A crystal structure determination has shown that this binuclear complex contains two Re(CO)3 fragments which are bridged by a chloride and a heavily constrained salophenH– anion as ligands. Under ambient conditions in solution and in the solid state, the complex displays an orange emission which originates from the lowest-energy IL/MLCT triplet. In solution, this phosphorescence is completely quenched by oxygen.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2019-0211/pdf

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