Effect mechanism of acidification and vulcanization on SBS-modified asphalt

Author:

Zhang Feng1,Li Lei1

Affiliation:

1. College of Civil Engineering, Fuzhou University , Fuzhou , 350116 , P. R. China

Abstract

Abstract A styrene-butadiene-styrene (SBS) modified asphalt compound was prepared by the addition of polyphosphoric acid (PPA) and sulfur. The effect of PPA and sulfur on major physical properties, including toughness and tenacity, aging resistance, and storage stability was investigated. The structural characteristics of SBS-modified (SM) asphalt, SBS/PPA-modified (SPM) asphalt, and SBS/PPA/sulfur-modified (SPSM) asphalt were investigated using scanning electron microscopy (SEM), gel filtration chromatography (GPC), and thermal analysis. It has been found that acidification prompted the clustering of SBS particles and confined the swelling of SBS, making SPM asphalt more susceptible to aging. Vulcanization changed the morphological characteristics of SBS in asphalt, improved the compatibility between SBS and asphalt, and weakened the aging susceptibility. Therefore, it is reasonable to modify SM asphalt by using PPA and sulfur together.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Polymers and Plastics,General Chemical Engineering

Reference25 articles.

1. ASTM D5976 (2001). Standard specification for type I polymer modified asphalt cement for use in pavement construction.

2. ASTM D5801-95 (2006). Standard test method for toughness and tenacity of bituminous materials.

3. Baumgardner, G.L. and Masson, J.F. (2005). Polyphosphoric acid modified asphalt: proposed mechanisms. Proc. Assoc. Asphalt Paving Technol. 74: 283–305.

4. Gao, J.L. (2005). Analysis and evaluation of bitumen new index and additive index, Doctor Thesis. Southeast University, Nanjing, PRC.

5. Gao, J.L., Huang, X.M., and Li, H.J. (2005). Evaluation method of differential scanning calorimetry for asphalt performance (Chinese). J. Traff. Tran. Eng. 5: 37–42.

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