Affiliation:
1. Institut für Theoretische Chemie und Strahlenchemie der Universität Wien und Ludwig-Boltzmann-Institut für Strahlenchemie, Wien, Austria
Abstract
The radiolysis of methanol in the presence of air as well as of pure oxygen (1 to 5atm) was investigated, the yields of the major products: carboxylic acids (by far predominantly formic acid), oxalic acid, formaldehyde and glycolaldehyde were determined as a function of the absorbed dose. In addition small amounts (G≤0.05) of glyoxal, glyoxalic acid and glycolic acid were also detected. Based on the results a possible reaction mechanism is presented.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
5 articles.
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