The Microwave Spectrum of 15N-Difluoroacetonitrile: Electric Dipole Moment and Partial r0-Structure-Reference-Cited by-同舟云学术

The Microwave Spectrum of 15N-Difluoroacetonitrile: Electric Dipole Moment and Partial r0-Structure

Published:1991-06-01 Issue:6 Volume:46 Page:535-539
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Ohle Bettina¹,Mäder Heinrich¹,Guarnieri Antonio¹

Affiliation:

1. Abteilung Chemische Physik im Institut für Physikalische Chemie der Universität Kiel, Kiel

Abstract

Abstract The rotational spectrum of 15N-difluoroacetonitrile has been investigated in the frequency range from 8 to 18 GHz. From the measured lines with J up to 20, rotational constants and quartic centrifugal distortion constants have been determined. For some lines the Stark effect has been examined, yielding the components of the electric dipole moment along the a- and c-principal axes of inertia. The obtained rotational constants were also used together with the rotational constants of the normal isotopomer to derive a partial restructure of the molecule

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1991-0609/pdf

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5. a;Andolfatto;Naturforsch,1988

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