A Spin Trap Investigation of Azolyl Radicals

Author:

Babin V. N.1,Gumenyuk V. V.1,Solodovnikov S. P.1,Belousov Yu. A.1

Affiliation:

1. The Institute of Organoelement Compounds Academy of Sciences of the USSR, Vavilova 28, Moscow 117 813, USSR

Abstract

Abstract An ability of azolyl-anions to behave as one-electrons reductans in reactions with f-nitro-sobutane and iron carbonyls are found in solu-tions. The azolyl radicals formed in reaction of azolyl-anions and azoles with t-BuNO have been trapped as corresponding nitroxide radicals. The formation of radicals from azoles can be described as consequence of proton and electron transfer acts.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 17 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Reactions of ferricinium salts with Lewis bases;Russian Chemical Bulletin;2011-10

2. Vinylpyrroles;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

3. The Coordination Chemistry of Pyrazole-Derived Ligands;Progress in Inorganic Chemistry;2007-03-09

4. Organometallic complexes of polyheteroatom azoles other than pyrazole;Advances in Heterocyclic Chemistry;2002

5. Organometallic complexes of pyrazoles;Advances in Heterocyclic Chemistry;2001

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