Affiliation:
1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule Darmstadt, Hochschulstraße 4, D-6100 Darmstadt
Abstract
Abstract
The new oxide pnictides Ba2Mn2Sb2O and Ba2Mn2Bi2O crystallize in the hexagonal system (space group P63/mmc) with the following constants:
Ba2Mn2Sb2O: a = 471 ± 1 pm, c = 2004 ± 2 pm, c/a = 4.255,
Ba2Mn2Bi2O: a = 480.3 ± 0.5pm, c = 2009.7 ± 1.0pm, c/a = 4.184.
The Mn and Sb(Bi) atoms form corrugated hexagonal nets. These nets are bridged between the Mn atoms by O atoms to double layers separated by Ba atoms.
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