Käfigverbindungen im System P4S3-As4S3 / Cage Compounds in the System P4S3-AS4S3

Abstract

Mixtures of P4S3 and As4S3 were investigated. The system reveals a broad metastable region of solid solubility. At the composition PAs3S3 new structures are obtainable after various thermal treatments. In the mixtures six different cage molecules (P4-xAsxS3 (x=1−3)) were found. PAs3S3 is the most stable of the mixed cages. At higher temperature a plastic-crystalline modification, at the composition PAs3S3 two further high temperature modifications are observed. NMR and mass spectra, and d-values of the modifications are reported, and the high temperature behaviour of all mixed cages is described.