Additionsverbindungen aus Trimethylstibindihalogeniden und Antimon(III)-halogeniden / Addition Compounds of Trimethylstibine Dihalogenides and Antimony(III) Halogenides

Abstract

Trimethylstibine dichloride and dibromide, resp., react with antimony(III) chloride and bromide, resp., to yield the 1:1 addition compounds (CH3)3SbCl2 · SbCl3 (1) and (CH3)3SbBr2 · SbBr3 (2). The crystal and molecular structure of 1 and 2 are determined by X-ray analysis, the Raman spectra discussed and assigned