Affiliation:
1. Institut für Anorganische Chemie der Universität zu Köln, Greinstraße 6, D-5000 Köln 41
Abstract
Abstract
Four new ternary compounds KB2X2 (B = Fe, Co, Rh; X = P, As) were prepared. They are isotypic and crystallize in a ThCr 2Si2-type structure (I4/mmm) with the following lattice constants:
KFe2As2: a = 384.2 pm c = 1386.1 pm
KCO2AS2: a = 379.4 pm c = 1357.0 pm
KRh2As2 : a = 398.7 pm c = 1326.7 pm
KRh2P2 : a = 388.4 pm c = 1298.6 pm
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