Affiliation:
1. 1Laboratorium für Anorganische und Analytische Chemie der Universität Tübingen
Abstract
The compounds Li3MeF6 (Me = Al, Ga, Ti, V, Cr and Fe) were prepared by reaction of LiF and MeF3. We obtained the orthorhombic α-modifications on quenching, on cooling slowly the β-modifications are formed, which crystallise monoclinic, space group C62h (C2/c) or Cs4 (Cc). DTA-measurements on α-Li3VF6 and the densities of both modifications suggest the α-modification to be the thermodynamical stable phase at room temperature.
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21 articles.
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