Die Reduktion von Tetrachlorkohlenstoff durch hydratisierte Elektronen, Η-Atome und reduzierende Radikale / The Reduction of Carbon Tetrachloride by Hydrated Electrons, H-Atoms, and Reducing Radicals

Abstract

The reduction of carbon tetrachloride by hydrated electrons, H atoms and reducing radicals has been investigated by pulse radiolysis conductivity methods. It has been found that one Cl® ion is formed per reducing species. A chain reaction is observed in the γ-radiolysis of solutions of CCl4 and iso-propanol, diethylether, and tetrahydrofurane. Mechanisms and kinetic data are discussed.