Affiliation:
1. Institut für Anorganische Chemie II der Universität Erlangen-Nürnberg
Abstract
When [Cr2 (CO)10]2⊖ or [Fe2 (CO) 8]2⊖ is reacted with Hg i. e. with group II metals at long reaction times above 100 °C insertion of the named metals into the Cr-Cr i. e. Fe-Fe bond of the both carbonylmetalates occurs yielding the new anionic complexes [(OC) 5Cr- Hg- Cr (CO) 5]2⊖
i. e. [(OC) 4Fe-M-Fe (CO)4]2⊖ (M = Zn, Cd, Hg). The properties of the compounds as well as their IR and Raman spectra will be discussed.
Cited by
14 articles.
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1. Systematic syntheses of [Hg{M(CO)4}2]2−, [Hg{M(CO)4}]x (M=Fe, Ru, Os), and structures of [Hg{M(CO)4}2]2− (M=Ru, Os);Journal of Organometallic Chemistry;1998-07
2. Synthetic, spectroscopic and structural studies on phosphine-stabilised [PPh3, Ph2PCH2PPh2, Ph2P(CH2)4PPh2, (Ph2P)C5H4N] main group element–iron–silicon chain complexes;J. Chem. Soc., Dalton Trans.;1994
3. Anionic trimetallic compounds containing FeEM skeletons (E = Zn, Cd, Hg; M = Fe, Mo, W). Crystal structure of [N(PPh3)2]2[(OC)4FeHgFe(CO)4];Journal of Organometallic Chemistry;1989-11
4. Compounds with Bonds between Transition Metals and either Mercury, Cadmium, Zinc or Magnesium;Comprehensive Organometallic Chemistry;1982
5. Iron Compounds without Hydrocarbon Ligands;Comprehensive Organometallic Chemistry;1982