Electrical Conductivity of Magnesium Oxide/Molten Carbonate Eutectic Coexisting System-Reference-Cited by-同舟云学术

Electrical Conductivity of Magnesium Oxide/Molten Carbonate Eutectic Coexisting System

Published:2019-05-27 Issue:9 Volume:74 Page:739-742
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Nikolaeva Elena V.¹²,Bovet Andrey L.¹²,Zakiryanova Irina D.¹²

Affiliation:

1. Institute of High Temperature Electrochemistry, UB RAS , 620990 Yekatherinburg , Russia

2. Ural Federal University , 620002 Yekatherinburg , Russia

Abstract

Abstract The electrical conductivity of molten ternary alkali carbonate eutectic, coexisting with MgO particles, has been investigated. The conductivity was measured by the AC impedance method. The apparent activation energy ΔEa increased with the MgO content. This fact can be attributed to the effect of the solid phase. The specific conductivity of those systems could not be described using the Maxwell model over the solvation process of the carbonate ions on the particles of the magnesium oxide.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-2019-0109/pdf

Reference12 articles.

1. M. Mizuhata, Y. Harada, G. Cha, A. Béléké, and S. Deki, J. Electrochem. Soc. 151, 179 (2004).

2. D. Shores, J. Selman, S. Israni, and E. Ong, in: Molten Carbonate Fuel Cell Technology (Eds. J. R. Selman, D. A. Shores, H. C. Maru, and I. Uchida), PV 90-16, The Electrochemical Society Proceedings Series, Pennington 1990, p. 290.

3. M. Mizuhata, A. Béléké, H. Watanabe, Y. Harada, and S. Deki, Electrochim. Acta 53, 71 (2007).

4. M. Mizuhata, T. Ohashi, and A. Béléké, Int. J. Hydrogen Energy 37, 19407 (2012).

5. H. Nafe, J. Solid State Sci. Technol. 3, 7 (2014).

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Electrical Conductivity of Ceria-Based Oxides/Alkali Carbonate Eutectic Nanocomposites;Journal of The Electrochemical Society;2021-04-01